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Kinetics of proton-coupled electron-transfer reactions to the manganese-oxo “cubane” complexes containing the Mn(4)O [Formula: see text] and Mn(4)O [Formula: see text] core types
The kinetics of proton-coupled electron-transfer (pcet) reactions are reported for Mn(4)O(4)(O(2)PPh(2))(6), 1, and [Mn(4)O(4)(O(2)PPh(2))(6)](+), 1(+), with phenothiazine (pzH). Both pcet reactions form 1H, by H transfer to 1 and by hydride transfer to 1(+). Surprisingly, the rate constants differ...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | en |
| Publicado em: |
The National Academy of Sciences
2003
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC152986/ https://ncbi.nlm.nih.gov/pubmed/12644708 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0637229100 |
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