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Structure and Catalytic Mechanism of the Thioesterase CalE7 in Enediyne Biosynthesis
The biosynthesis of the enediyne moiety of the antitumor natural product calicheamicin involves an iterative polyketide synthase (CalE8) and other ancillary enzymes. In the proposed mechanism for the early stage of 10-membered enediyne biosynthesis, CalE8 produces a carbonyl-conjugated polyene with...
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| Main Authors: | , , , , , , , , , , |
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| Formato: | Artigo |
| Idioma: | English |
| Publicado em: |
American Society for Biochemistry and Molecular Biology
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2708871/ https://ncbi.nlm.nih.gov/pubmed/19357082 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.M809669200 |
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