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Comprehensive Structural Studies of 2′,3′-Difluorinated Nucleosides: Comparison of Theory, Solution, and Solid State

The conformations of three 2′,3′-difluoro uridine nucleosides were studied by X-ray crystallography, NMR spectroscopy, and ab initio calculations in an attempt to define the roles that the two vicinal fluorine atoms play in the puckering preferences of the furanose ring. Two of the compounds examine...

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Detalhes bibliográficos
Main Authors: Barchi, Joseph J., Karki, Rajeshri G., Nicklaus, Marc C., Siddiqui, Maqbool A., George, Clifford, Mikhailopulo, Igor A., Marquez, Victor E.
Formato: Artigo
Idioma:English
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2739414/
https://ncbi.nlm.nih.gov/pubmed/18558684
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja800964g
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